Victory at the Vicente Calderon tied in with Bayern Munich’s loss mean that Diego Simeone’s side go into their last group game with first place guaranteed.
Goals from Kevin Gameiro and Antoine Griezmann helped Atletico Madrid defeat PSV to seal first place in Champions League Group D with one game remaining.
Bayern Munich’s earlier defeat to Rostov means that Atletico are guaranteed top spot, as a strong second-half performance saw them win their fifth game from five.
Griezmann set up Gameiro for the opener, before getting his name on the scoresheet with a close-range finish.
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